Phone: (814) 898-6400
Fall 2016 Schedule
|Chemistry 106||Introductory and General Chemistry|
||Problem Solving in Chemistry|
||General Chemistry I|
|Chemistry 111||General Chemistry Laboratory I|
|Chemistry 111H||Honors General Chemistry Laboratory I|
|Chemistry 112||General Chemistry II|
||General Chemistry Laboratory II|
|Chemistry 213||Organic Chemistry Laboratory|
|Chemistry 400||Chemical Literature|
|Chemistry 413||Chemistry of the Elements|
|Chemistry 431W||Organic and Inorganic Preparations
|Chemistry 446||X-ray Crystallography|
. Oxygen is
transported through the blood by . A
B vitamin, contains cobalt and
in methanogenic bacteria converts carbon dioxide to methane. The naturally occurring molecules are often very complex and difficult to study because there are usually associated with proteins. One approach used to help chemists understand complex processes is to make model compounds which have characteristics similar to the natural molecule. Model compounds can often provide insight into the important factors of the structure of the naturally occurring complexes as well as giving information into the design of systems which can mimic biological behavior. Much of the research in this area has involved such topics as catalysis, organic synthesis, and analytical methods in both industrial and medicinal applications.
II. Another research project in my group involves the investigation of the geometry and coordination preferences of metal ion complexes with multidentate ligands. When a ligand has several possible coordination sites, the ones used in coordination depend on a combination of the preferred geometry of the metal ion, the hard/soft nature of the ligand and the metal ion, and the geometry of the ligand. We have been investigating a class of ligands based on di-2-pyridyl ketone (DPK). In particular, new ligands containing O, S, and N in 5- and 6- membered rings are being synthesized. The coordination of these ligands with a variety of transition metal ions can be studied through the use of X-ray crystallographic techniques.
"Steric Ligand Effects of Six Bidentate Bipyridyl Ligands," C.A. Bessel, J.A. Margarucci, J.H. Acquaye, R.S. Rubino, J. Crandall, A.J. Jircitano, and K.J. Takeuchi, Inorg. Chem., 1993, 32, 5779-5784.
"The Self-Condensation of a Derivative of o-Aminobenzaldehyde: The Structure of the Polycyclic, Bisanhydro-Trimer, " A.J. Jircitano, S.O. Sommerer, J.J. Shelley, B.L. Westcott, and I.-H. Suh, Acta Cryst., Sec. C., 1994, C50, 445-447.
"The Synthesis and Structure of Two Metal-Di-2-Pyridyl Ketone
Oxime Dimers," S.O. Sommerer, B.L. Westcott, A.J. Jircitano, and
K.A. Abboud, Inorg. Chim. Acta, 1995, 238,
"Crystal Structures of trans-[Ru(dppe)2(CO)(Cl)](BF4).toluene and trans-[Ru(dppm)2(CO)(Cl)](BF4).CH2Cl2: A Study of the Steric and Electronic Ligand Effects of trans-Positioned Diphosphine Ligands," L.F. Szczepura, J. Giambra, R.F. See, J. Lawson, R.S. Janik, A.J. Jircitano, M.R. Churchill, and K.J. Takeuchi, Inorg. Chim. Acta, 1995, 239, 77-85.
"Distortions from Trigonal Prismatic Geometry for Several Structurally Characterized Clathrochelate Complexes: Significance of p-Backbonding on Clathrochelate Coordination Geometry," S.A. Kubow, K.J. Takeuchi, J.J. Gryzbowski, A.J. Jircitano, and V.L. Goedken, Inorg. Chim. Acta, 1996, 241, 21-30.
"catena-Poly[m-O,m-N'(di-2-pyridyl ketone)-N',O)m-N(di-2-pyridyl ketone)-N',O]silver(I) Tetrafluoroborate," S.O. Sommerer, B.L. Westcott, A.J. Jircitano, and K.A. Abboud, Acta Cryst., Sec. C., 1996, C52, 1426-1428.
"trans-Bis[4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole-N',N']copper(II) Bis(tetrafluoroborate)," A. J. Jircitano, S. O. Sommerer and K. A. Abboud, Acta Cryst., Sec. C., 1997, C53, 434 - 436.
"Bis(di-2-pyridylmethanediol-N,N')palladium(II) Dichloride Tetrahydrate and Dichloro(di-2-pyridylmethanediol-N,N')gold(III) Chloride," S. O. Sommerer, A. J. Jircitano, B. L. Westcott, K. A. Abboud and J. A. Krause Bauer, Acta Cryst., Sec. C., 1997, C53, 707 - 710.
"Chlorobis(N, N'-di-2-pyridyl ketone oximato)gold(III) Hydrate," S. O. Sommerer, C. E. MacBeth, A. J. Jircitano and K. A. Abboud, Acta Cryst., Sec. C., 1997, C53, 1551 - 1553.
"trans-Diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) Tetrafluoroborate," S. O. Sommerer, T. L. Friebe, A. J. Jircitano, C. E. MacBeth and K. A. Abboud, Acta Cryst., Sec. C., 1998, C54, 178 - 179.
"Remarkable Spectator Ligand Effect on the Rate Constant of
Ligand Substitution of (Aqua)ruthenium(II) Complexes," M. H. V.
Huynh, J. M. Lasker, M. Wetzler, B. Mort, L. F. Szczepura, L. M.
Witham, J. M. Cintron, A. C. Marschilok, L. J. Ackerman, R. K.
Castellano, D. L. Jameson, M. R. Churchill, A. J. Jircitano, and
K. J. Takeuchi, J. Am. Chem. Soc.
123, 2001, 8780 - 8784.
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Last modified: May 9, 2016