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"Oxidative Rearrangements of arylalkanones with 1H-1-hydroxy-5-methyl-1,2,3-benziodoxathiole 3,3-dioxide" has been accepted for publication in Tetrahedron Letters

CHEM 210/212

Fall 2008

Syllabus - Fall 2008
Syllabus

Chapter 4
Problem Set:
1-16, 19-33, 36, 39-42, 45-61; Advanced Problems: 62, 65-68
Sections Covered: 1-6, 8-14

Chapter 5
Problem Set:
2-39, 41-46, 48, 49, 51-53, 55-58, ; Advanced Problems: 40, 47, 50, 54, 62-64
Sections Covered: 2-12

Chapter13
Problem Set:
6-14, 27-33; Advanced Problems: 15
Sections Covered: 4-7
Additional problems from outside the text posted below.

Exam 1 Key

IR Lecture

IR Study Guide/Problems

IR Study Guide Problems - KEY

IR Flowchart

Nomenclature Flowchart

Exam 2 Study Guide

Exam 2 Practice Exam

Exam 2 Practic Exam KEY

 

Hypervalent Iodine

While the idea of "hypervalent" iodine compounds may seem a difficult concept at first, the chemistry is easily related to the core concepts of basic organic chemistry.

For example, [hydroxy-(tosyloxy)iodo]benzene (HTIB) or Koser's reagent bascically functions as a highly evolved bromine analog. If you can think of a reaction of elemental bromine with an organic compound, you already know one of the reactions of HTIB!